Hybrid Materials from Ultrahigh‐Inorganic‐Content Mineral Plastic Hydrogels: Arbitrarily Shapeable, Strong, and Tough

 


Citation

 

Xiaotong Zhang, Baohu Wu, Shengtong Sun*, and Peiyi Wu*. Hybrid Materials from Ultrahigh‐Inorganic‐Content Mineral Plastic Hydrogels: Arbitrarily Shapeable, Strong, and Tough. Adv. Funct. Mater. 2020, ASAP.


 

Abstract

 

Natural mineralized structural materials such as nacre and bone possess a unique hierarchical structure comprising both hard and soft phases, which can achieve the perfect balance between mechanical strength and shape controllability. Nevertheless, it remains a great challenge to control the complex and predesigned shapes of artificial organic–inorganic hybrid materials at ambient conditions. Inspired by the plasticity of polymer‐induced liquid precursor phases that can penetrate and solidify in porous organic frameworks for biomineral formation, here a mineral plastic hydrogel is shown with ultrahigh silica content (≈95 wt%) that can be similarly hybridized into a porous delignified wood scaffold, and the resultant composite hydrogels can be manually made into arbitrary shapes. Subsequent air drying well preserves the designed shapes and produces fire‐retardant, ultrastrong, and tough structural organic–inorganic hybrids. The proposed mineral plastic hydrogel strategy opens an easy and eco‐friendly way for fabricating bioinspired structural materials that compromise both precise shape control and high mechanical strength.


 

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